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    • 专利摘要:
    The main object of the invention is a photovoltaic module (1) comprising at least a first transparent layer (3) forming the front face of the photovoltaic module (1) intended to receive a luminous flux, an assembly (4) of a a plurality of photovoltaic cells (5) arranged side by side and electrically connected to one another, an encapsulating assembly (6a, 6b), the plurality of photovoltaic cells (5), and a second layer (7) forming the rear face of the photovoltaic module (1). ), the encapsulating assembly (6a, 6b) and the assembly (4) of a plurality of photovoltaic cells (5) being located between the first (3) and second (7) layers. The photovoltaic module (1) is characterized in that the first layer (3) consists of at least one transparent polymeric material and has a plurality of plates (8) independent of each other, each plate (8) being located in viewing at least one photovoltaic cell (5), so as to form a discontinuous front face of the photovoltaic module (1), and in that the rigidity of the encapsulating assembly (6a, 6b) is defined by a Young's modulus (E) encapsulation material greater than or equal to 75 MPa at room temperature and a thickness (e) of the encapsulating assembly (6a, 6b) of between 0.4 and 1 mm.
    公开号:FR3024281A1
    申请号:FR1457277
    申请日:2014-07-28
    公开日:2016-01-29
    发明作者:Julien Gaume；Stephane Guillerez；Lionel Sicot
    申请人:Commissariat a lEnergie Atomique CEA；Commissariat a lEnergie Atomique et aux Energies Alternatives CEA；
    IPC主号:
    专利说明:

    [0001] TECHNICAL FIELD The present invention relates to the field of photovoltaic modules, comprising a set of photovoltaic cells interconnected electrically, and in particular so-called "crystalline" photovoltaic cells, that is to say which are based on silicon crystals or silicon polycrystals. The invention can be implemented for many applications, being particularly concerned by applications that require the use of lightweight photovoltaic modules, flexible and robust against shocks and high mechanical loads. It can thus be applied in particular for buildings such as residential or industrial premises, for example for the realization of their roofs, for the design of street furniture, for example for public lighting, road signs or the recharge of buildings. electric cars, or also for its integration in trafficable areas, for pedestrians and / or vehicles, such as roadways or roads, cycle paths, industrial platforms, squares, sidewalks, among others. This latter application is commonly referred to as the "solar road".
    [0002] The invention thus proposes a photovoltaic module that is particularly suitable for being applied to a rigid support, a photovoltaic structure assembly comprising such a photovoltaic module, the use of such a photovoltaic module for its application on a rigid support, as well as a method of producing such a module or such a photovoltaic structure assembly. STATE OF THE PRIOR ART A photovoltaic module is an assembly of photovoltaic cells arranged side by side between a first transparent layer forming a front face of the photovoltaic module and a second layer forming a rear face of the photovoltaic module.
    [0003] The first layer forming the front face of the photovoltaic module is advantageously transparent to allow the photovoltaic cells to receive a luminous flux. It is traditionally made of a single glass plate, having a thickness of about 3 mm. The second layer forming the rear face 5 of the photovoltaic module can in turn be made of glass, metal or plastic, among others. It is usually formed by a polymeric structure based on an electrically insulating polymer, for example of the polyethylene terephthalate (PET) or polyamide (PA) type, which can be protected by one or more layers based on fluorinated polymers, such as polyvinyl fluoride (PVF) or polyvinylidene fluoride (PVDF), and having a thickness of the order of 300 μm. The photovoltaic cells can be electrically connected in series with each other by means of front and rear electrical contact elements, called connection conductors, and formed for example by copper strips, respectively arranged against the front faces (faces facing the front panel of the photovoltaic module 15 for receiving a luminous flux) and rear (faces facing the rear face of the photovoltaic module) of each of the photovoltaic cells. Furthermore, the photovoltaic cells, located between the first and second layers respectively forming the front and rear faces of the photovoltaic module, are encapsulated. In a conventional manner, the encapsulant chosen corresponds to a polymer of the elastomer (or rubber) type, and may for example consist of the use of two layers (or films) of poly (ethylene-vinyl acetate) (EVA) between which the photovoltaic cells and the cell connecting conductors are arranged. Each EVA layer may have a thickness of at least 0.3 mm and a Young's modulus less than or equal to 30 MPa at room temperature. Usually again, the method for producing the photovoltaic module comprises a single rolling step of the various layers described above, at a temperature greater than or equal to 140 ° C. or even 150 ° C., and for a period of at least 8 minutes, even 15 minutes. After this rolling operation, the two EVA layers melt to form a single layer in which the photovoltaic cells are embedded. Nevertheless, these prior art known embodiments of a photovoltaic module are not entirely satisfactory and have several disadvantages for at least some of their applications. For example, in the context of the application of the solar road type, a need has arisen to use roads or roadways as means of energy production during the day, whether to supply buildings located nearby (companies, eco neighborhoods, solar farms, individual houses, among others) or to feed the power grid or traffic assistance devices, for example. Thus, first of all, the presence of a glass plate to form the front face of the photovoltaic module is not compatible with certain applications of the photovoltaic module that may require a relative lightness and ease of formatting of the module. In contrast, prior art designs using glass on the front side of photovoltaic modules involve obtaining a high module weight and limited integration capability. For an application of the solar road type, the photovoltaic modules with a front face made of glass are, on the one hand, not flexible enough to respond to the deformation of a road, this being of the order of mm every 100 mm for the two horizontal axes, according to the width and the length, of the road. On the other hand, these photovoltaic modules are not sufficiently resistant to static charge if they are glued directly to the roadway. In other words, the roughness of the pavement can cause punching of the photovoltaic cells by the rear face of the photovoltaic module, thus causing risks of breakage of the photovoltaic cells.
    [0004] Solutions have been envisaged for replacing the glass front of photovoltaic modules with plastics while retaining the conventional photovoltaic module architecture and method. By way of examples, patent application FR 2 955 051 A1 and international applications WO 2012/140585 A1 and WO 2011/028513 A2 describe possibilities of alternatives to glass for designing the front face of photovoltaic modules, among which: use of 3024281 4 polymer sheets, less than or equal to 500 μm thick, such as polyvinylidene fluoride (PVDF), ethylene tetrafluoroethylene (ETFE), polymethyl methacrylate (PMMA) or polycarbonate (PC ). However, the simple substitution of the glass with a polymeric material, in order to obtain a light and flexible photovoltaic module, generally leads to an increased vulnerability of the module to shocks and mechanical loads, which is not acceptable for certain applications. In addition, in these prior art embodiments, the front (glass-free) face of each photovoltaic module is continuous, i.e. it forms a unitary sheet or plate which covers the entire surface of the photovoltaic module. whole module. In this way, the flexibility of each photovoltaic module can be limited and above all not sufficient. Moreover, this also poses a problem of accentuation of differential expansion stresses between the different layers of the structure, which can lead to undesirable deformations or detachments at the interfaces of the structure, for example at the encapsulant / layer interface external. Some solutions have been proposed to obtain a relative discontinuity of the front face of a photovoltaic module in order to obtain a better flexibility of the module and to better manage the differential expansion stresses. Thus, for example, US patent application 2014/0000683 A1 discloses a method for encapsulating photovoltaic cells individually. The encapsulated cells can then be interconnected to obtain a flexible photovoltaic module. Furthermore, the patent application US 2014/0030841 A1 teaches the implementation of a photovoltaic module on a flexible substrate. The photovoltaic module is composed of "submodules" consisting of interconnected photovoltaic cells, each submodule being electrically independent of the neighboring submodules. However, the solutions described above are not totally satisfactory in terms of flexibility, resistance to shocks and mechanical loads, performance and cost of photovoltaic modules, in particular for constraining applications that require them strongly at the same time. their mechanical strength.
    [0005] SUMMARY OF THE INVENTION There is thus a need to propose an alternative solution for designing a photovoltaic module to meet at least some of the constraints inherent to the applications targeted by the use of the photovoltaic module, in particular to improve flexibility. , the rigidity, the lightness and the resistance to shocks and mechanical loads of the photovoltaic module. The object of the invention is to remedy at least partially the needs mentioned above and the drawbacks relating to the embodiments of the prior art. The invention thus has, according to one of its aspects, a photovoltaic module, suitable in particular for being applied on a rigid support, comprising at least: a first transparent layer forming the front face of the photovoltaic module intended for receive a luminous flux, - a set of a plurality of photovoltaic cells arranged side by side and electrically connected to each other, - an assembly encapsulating the plurality of photovoltaic cells, - a second layer forming the rear face of the photovoltaic module, intended for particular to be secured to a rigid support, the encapsulating assembly and the set of a plurality of photovoltaic cells being located between the first and second layers, characterized in that the first layer consists of at least one polymer material transparent and has a plurality of plates independent of each other, each plate being located facing at least one photovoltaic cell, so as to form a discontinuous front face of the photovoltaic module, and in that the rigidity of the encapsulating assembly is defined by a Young's modulus of the encapsulation material greater than or equal to 75 MPa at room temperature and a thickness of the entire encapsulant between 0.4 and 1 mm. Initially, that is to say before any rolling operation, the encapsulating assembly consists of two layers of encapsulation material, called core layers, between which the set of a plurality of photovoltaic cells is 3024281 6 encapsulated. However, after the layer rolling operation, the layers of encapsulation material have melted to form a single layer (or assembly) in which the photovoltaic cells are embedded. Prior to any rolling operation, each layer of encapsulation material may thus have a rigidity defined by a Young's modulus at ambient temperature of the encapsulation material greater than or equal to 75 MPa and a thickness of the layer of between 0.2. and 1 mm, or even between 0.2 and 0.5 mm. The assembly encapsulating the plurality of photovoltaic cells is thus constituted by the two layers of encapsulation material, namely the layers of encapsulation material which before rolling are in direct contact with the photovoltaic cells. The term "transparent" means that the material of the first layer forming the front face of the photovoltaic module is at least partially transparent to visible light, allowing at least about 80% of this light to pass through.
    [0006] Moreover, by the expression "plates independent of each other" is meant that the plates are located at a distance from each other, each forming a unitary element independent of the first layer and from each other, superimposed on less a photovoltaic cell. The meeting of all these plates then forms the first layer with a discontinuous appearance.
    [0007] Furthermore, by the term "encapsulant" or "encapsulated", it should be understood that the set of a plurality of photovoltaic cells is arranged in a volume, for example hermetically sealed, at least partially formed by the layers of material encapsulation, joined together after rolling. The photovoltaic module may be applied on a rigid support, which may, in a particular embodiment of the invention, be a circulable zone. "Circumable zone" means any zone intended for the circulation of pedestrians and / vehicles, such as for example a road (or road), a motorway, a cycle path, an industrial platform, a square, a sidewalk, list being in no way limiting.
    [0008] Moreover, the expression "ambient temperature" means a temperature of between approximately 15 and 30 ° C. Thanks to the invention, it may thus be possible to provide an alternative solution for the design of a flexible and relatively flexible photovoltaic module, and also sufficiently robust to withstand shocks and mechanical loads experienced, especially after application on a rigid support. In particular, the use of a discontinuous front face can confer on the photovoltaic module according to the invention a flexible character, in particular making it easier to apply to a non-flat support, for example curved. In addition, the use of a high rigidity encapsulation material for the encapsulating photovoltaic cell assembly can adequately protect the photovoltaic cells against the risk of a high mechanical load or shock, by limiting their flexion, and thus limiting the risk of breakage. In addition, the absence of use of a glass material for the front face of the photovoltaic module can enable the photovoltaic module according to the invention to have a weight lower than that of a photovoltaic module according to the prior art. typically of the order of 12 kg / m 2, depending on the thickness of the different layers used. Finally, the use of a discontinuous front face made of a polymer material may make it possible to guard against problems of thermal expansion during the use of the photovoltaic module according to the invention outside. Indeed, the thermal expansion being proportional to the dimensions of the first layer forming the front face of the module, the fact of using plates having dimensions close to those of the photovoltaic cells can significantly limit the displacements induced by thermal stresses that can give rise to delamination or uncontrolled conformation of the photovoltaic module. The photovoltaic module according to the invention may further comprise one or more of the following characteristics taken separately or in any possible technical combination. The second layer forming the rear face of the photovoltaic module may also be discontinuous. In other words, the second layer may also comprise a plurality of plates independent of each other, each plate being located facing, that is to say superimposed, at least one photovoltaic cell. The presence of a discontinuous rear face on the photovoltaic module according to the invention may for example make it possible to further improve the flexibility of the module to facilitate its application to a rigid support provided with a surface roughness. Moreover, even though the first layer forming the front face of the photovoltaic module according to the invention, and possibly the second layer forming the rear face of the module, have a discontinuous appearance, the set of a plurality of photovoltaic cells and the encapsulating assembly are advantageously continuous.
    [0009] According to a particular embodiment of the invention, each plate of the first layer, and possibly of the second layer, may be located opposite several photovoltaic cells. This may especially be the case for photovoltaic cells of smaller dimensions than those of conventional photovoltaic cells, typically 156 x 156 mm.
    [0010] In addition, when a single photovoltaic cell is located facing each plate of the first layer, and possibly of the second layer, each plate may have dimensions at least equal to those of the photovoltaic cell to which it is superimposed. The photovoltaic module is advantageously devoid of a first layer forming the front face of the module made of glass. Thus, as indicated above, it may be possible to improve the lightness and the integration capacity of the photovoltaic module. The encapsulation material forming the two layers of core encapsulation material of the encapsulant assembly may have a Young's modulus at room temperature greater than or equal to 100 MPa, in particular greater than or equal to 150 MPa, or even 200 MPa. It is in particular 220 MPa. The encapsulant assembly may be formed from two layers of encapsulating material having the same or different thicknesses. The second layer forming the rear face of the photovoltaic module may consist of at least one polymeric material.
    [0011] In a variant, the second layer forming the rear face of the photovoltaic module may consist of at least one composite material, in particular of the polymer / glass fiber type. The second layer preferably also has a coefficient of thermal expansion less than or equal to 20 ppm, and preferably less than or equal to 10 ppm. The second layer forming the rear face of the photovoltaic module may or may not be transparent. The rigidity of the second layer forming the rear face of the photovoltaic module can be defined by a stiffness factor, corresponding to the Young modulus at room temperature of the material of the second layer multiplied by the thickness of the second layer, between 5. and 15 GPa.mm. In addition, the rigidity of the second layer forming the rear face of the photovoltaic module can be defined by a Young's modulus at room temperature of the material of the second layer greater than or equal to 1 GPa, better still greater than or equal to 3 GPa, better than or equal to 10 GPa, and a thickness of the second layer of between 0.2 and 3 mm. In this way, the second layer forming the rear face of the photovoltaic module can have a high rigidity, which can thus limit its flexibility. However, this high rigidity can make it possible to reduce or even prevent the punching of photovoltaic cells by the rear face of the module, that is to say the appearance of cracks and / or breaks in the photovoltaic cells, when it is applied on a support having a large surface roughness. The spacing between two adjacent photovoltaic cells, or consecutive or adjacent cells, may be greater than or equal to 1 mm, in particular between 1 and 30 mm, and preferably greater than or equal to 3 mm, in particular between 10 and 20 mm . The two neighboring photovoltaic cells considered may be two neighboring cells of the same series (also referred to as "string" in English) or two neighboring cells respectively belonging to two consecutive series of the set of photovoltaic cells.
    [0012] The presence of a large spacing between the photovoltaic cells can make it possible to obtain an equally important spacing between the plates of the first layer forming the front face of the photovoltaic module. In this way, the discontinuous appearance of the front face of the module is accentuated, thus allowing the module to be given flexibility to facilitate its application to the rigid support. Advantageously, the spacing between two adjacent plates of the first layer, and possibly the second layer, is less than or equal to the spacing between two neighboring photovoltaic cells. According to one variant, the photovoltaic module may comprise an intermediate layer called "damping" layer located between the first layer forming the front face of the photovoltaic module and the assembly encapsulating the plurality of photovoltaic cells, allowing the assembly, in particular by gluing, of the first layer on the encapsulating set. The intermediate layer may consist of at least one polymeric material, especially a thermoplastic or thermosetting polymer resin. The intermediate layer may be for example in sheet form or in liquid form. It can be adhesive, for example of the PSA type, or not. It can be carried out hot or at room temperature. The rigidity of the intermediate layer can be defined by a Young modulus of the intermediate layer material of 50 MPa or less at room temperature and a thickness of the intermediate layer of between 0.01 and 1 mm. The intermediate layer can in particular fulfill two main functions. On the one hand, it can allow the adhesion of the first layer forming the front face of the photovoltaic module to the encapsulating assembly for the case where the two layers are not chemically compatible. On the other hand, it can create in the photovoltaic module a "damping" layer of flexibility to improve the impact resistance and mechanical loads of the module. This intermediate layer may be optional, in particular absent when there is chemical compatibility between the first layer forming the front face of the photovoltaic module and the encapsulating assembly.
    [0013] The photovoltaic module may further comprise an adhesive layer located between the second layer forming the rear face of the photovoltaic module and the assembly encapsulating the plurality of photovoltaic cells, enabling the assembly, particularly by bonding, of the second layer on the photovoltaic module. encapsulating set.
    [0014] By "adhesive layer" is meant a layer allowing, once the photovoltaic module is made, the second layer to adhere to the encapsulating assembly. This is a layer for chemical compatibility and adhesion between the encapsulant and the back side. Furthermore, the thickness of the first layer forming the front face of the photovoltaic module may be greater than or equal to 0.1 mm, in particular between 0.5 and 6 mm. In addition, the invention further relates, in another of its aspects, to a photovoltaic structure assembly, comprising: a rigid support, a photovoltaic module as defined above, and a fixing layer, particularly by bonding, located between the rigid support and the photovoltaic module, allowing the adhesion of the photovoltaic module to the rigid support. The rigid support may have a surface roughness.
    [0015] According to an alternative embodiment, the fixing layer may consist of a bituminous adhesive. The use of the fixing layer may make it possible to obtain a rear face of the reinforced photovoltaic module, making it possible to avoid the risk of punching the photovoltaic cells by the rear face when the rigid support has a high surface roughness and the Photovoltaic module is subjected to shock or high mechanical load. Indeed, the interface between the rear face of the module and the rigid support can be filled by a protective binder. In addition, the invention also relates, in another of its aspects, to the use, for its application on a rigid support of a photovoltaic module 30 comprising at least: a first transparent layer forming the front face photovoltaic module intended to receive a luminous flux, - a set of a plurality of photovoltaic cells arranged side by side and electrically connected to each other, - an assembly encapsulating the plurality of photovoltaic cells, - a second layer forming the rear face of the photovoltaic cell. photovoltaic module, the encapsulant assembly and all of a plurality of photovoltaic cells being located between the first and second layers, the first layer consisting of at least one transparent polymeric material being polymethyl methacrylate (PMMA) shock nanostructured, and having a plurality of plates independent of each other, each plate being located e n view of at least one photovoltaic cell, so as to form a discontinuous front face of the photovoltaic module, and the rigidity of the encapsulating assembly being defined by a Young's modulus of the encapsulation material greater than or equal to 75 MPa at ambient temperature and a thickness of the encapsulating assembly of between 0.4 and 1 mm, the photovoltaic module being applied to the rigid support by means of a fixing layer. In another aspect, the invention also relates to a method for producing a photovoltaic module as defined above or to a photovoltaic structure assembly as defined above, comprising at least the two following successive steps of: a) hot rolling at a temperature above 150 ° C, all the constituent layers of the photovoltaic module except the first layer forming the front face of the photovoltaic module and a possible intermediate layer called "damping" located between the first layer and the assembly encapsulating the plurality of photovoltaic cells, b) rolling at a temperature less than or equal to 150 ° C, better 125 ° C, for example at room temperature, of the first layer forming the front face. of the photovoltaic module, and of the optional intermediate layer, on the layers 3024281 13 constituting the laminated photovoltaic module together during the first step a). In the first rolling step a), the constitutive layers of the photovoltaic module concerned are thus the set of a plurality of photovoltaic cells, the encapsulating assembly and the second layer forming the rear face of the photovoltaic module. The optional intermediate layer called "damping" can facilitate the bonding of the first layer forming the front of the module on the other layers. This intermediate layer is optional. In particular, it may not be necessary when there is chemical compatibility between the first layer forming the front face of the module and the encapsulating assembly. Advantageously, the implementation of at least two rolling steps in the process according to the invention for the production of the photovoltaic module can make it possible to overcome any thermal expansion problems that may arise due to the use of a front face of the module made of a polymer material. Indeed, some layers of the photovoltaic module need to be laminated at a temperature greater than or equal to 140 ° C, or even 150 ° C, but rolling at this temperature level in a single step, in accordance with the practice according to the art Prior to this, all the layers of the module, including the one forming the front face of the module, can give rise to an uncontrolled conformation and to significant delaminations of the front face of the photovoltaic module because of excessive mechanical stresses generated. . Also, the presence of at least a second rolling step at a lower temperature than for the first step, for rolling the front face of the photovoltaic module, possibly combined with the presence of an intermediate layer called "damping" enabling gluing the front face of the module on the encapsulation material and the damping of thermal stresses, can limit or even prevent thermal expansion. Alternatively, the invention also relates, according to another of its aspects, to a method of producing a photovoltaic module as defined previously or to a photovoltaic structure assembly as defined above, comprising the single next step of: c) hot rolling at a temperature greater than or equal to 150 ° C of all the constituent layers of the photovoltaic module.
    [0016] For the realization of a photovoltaic structure assembly as defined above, steps a) and b), or step c), may be followed by step d) of fixing the photovoltaic module on a rigid support for forming the photovoltaic structure assembly, by means of a fixing layer of the photovoltaic structure assembly, constituted for example by a bituminous adhesive.
    [0017] As indicated above, the thickness of the encapsulating assembly may be between 0.4 and 1 mm, this resulting from the rolling association of at least two layers of encapsulation material each having a thickness of between 0.2 and 0.5 mm. These two layers of encapsulating material may also have different thicknesses.
    [0018] The photovoltaic module, the photovoltaic structure assembly and the method according to the invention may comprise any of the previously mentioned characteristics, taken alone or in any technically possible combination with other characteristics. BRIEF DESCRIPTION OF THE DRAWING The invention will be better understood on reading the following detailed description of an example of non-limiting implementation thereof, as well as on examining the single FIGURE. schematic and partial, of the accompanying drawing, illustrating, in section and in exploded view, an embodiment of a photovoltaic structure assembly comprising a photovoltaic module according to the invention.
    [0019] In this single figure, the different parts shown are not necessarily in a uniform scale, to make the figure more readable.
    [0020] DETAILED DESCRIPTION OF A PARTICULAR EMBODIMENT Reference is made here to FIG. 1, illustrating in section and in exploded view an exemplary embodiment of a photovoltaic structure assembly 10 comprising a photovoltaic module 1 conforming to FIG. 'invention.
    [0021] It should be noted that FIG. 1 corresponds to an exploded view of the photovoltaic structure assembly 10 before the rolling steps of the method according to the invention. Once the rolling steps have been performed, the different layers are in fact superimposed on each other, but also a little deformed so that at least the plates 8 of the first layer 3 sink into the assembly formed by the layer intermediate 9 and 10 encapsulating assembly 6a, 6b which deform. The rolling steps provide hot and vacuum pressing. Depending on the thicknesses of the different layers, the plates 8 may or may not be flush with the photovoltaic module 1, the material of the intermediate layer 9 and possibly that of the encapsulating assembly 6a, 6b may also fill at least part of the spaces between the plates 8.
    [0022] As explained above, the photovoltaic module 1 according to the invention is designed to be sufficiently flexible so as to be able to apply it, in particular by gluing, to a rigid support 2, which may have a surface roughness, in other words not necessarily plane and smooth. In addition, the photovoltaic module 1 according to the invention is also designed to withstand static or dynamic pressures of up to 1500 kN / m 2, or even 5000 kN / m 2. The rigid support 2 is advantageously sufficiently rigid not to deform when applying the same stress as that applied to the photovoltaic module 1. It may for example be formed by a roof covering, be concrete or sheet metal, among others.
    [0023] As can be seen in FIG. 1, the photovoltaic module 1 comprises a first transparent layer 3 forming the front face of the module 1 intended to receive a luminous flux, an encapsulating assembly 6a, 6b, obtained by the fusion of two layers. of upper encapsulation material 6a and lower 6b, a set 4 of photovoltaic cells 5 taken between the two layers of upper encapsulation material 6a and lower 6b, and a second layer 7 forming the rear face of the photovoltaic module 1 for The two encapsulating material layers 6a and 6b forming the encapsulating assembly, as well as any intermediate layer 9 described below, form a relatively flexible structure which can be made from a single material or several materials in the event of chemical incompatibility. According to the invention, the first layer 3 consists of a transparent polymer material and comprises a plurality of plates 8 independent of each other, each plate 8 being located facing a photovoltaic cell 5, 10 so as to form a discontinuous front face of the photovoltaic module 1. The transparent polymer material of the first layer 3 can for example be chosen from polycarbonate (PC), polymethyl methacrylate (PMMA), ethylene tetrafluoroethylene (ETFE), or polyfluoride vinylidene (PVDF), among others. In addition, the thickness of the first layer 3 may be greater than 0.1 mm, and ideally between 0.5 and 6 mm. In this example, the first layer 3 thus consists of several plates 8, of dimensions equal to 162 x 162 mm, PMMA of thickness equal to 3 mm. Furthermore, the photovoltaic cells 5 are electrically interconnected with each other with a spacing s between two adjacent cells 5 between 1 and 30 mm. The photovoltaic cells 5 may be so-called "crystalline" cells, that is to say based on silicon crystals or silicon polycrystals, with a homojunction or heterojunction, and with a thickness of less than or equal to 250 μm. Moreover, in this example, each plate 8 extends in superposition on both sides of the underlying photovoltaic cell 5 over a distance of about 3 mm, so that the spacing between two adjacent plates 8 here is equal to the spacing s between two neighboring cells decreased by about 2 times 3 mm, or about 6 mm. In addition, the rigidity of each layer of encapsulation material 6a and 6b is defined by a Young's modulus E at ambient temperature of the encapsulation material greater than or equal to 50 MPa, or even 75 MPa or even 100 MPa, of 3024281 Preferably greater than or equal to 200 MPa, and a thickness e of the layer 6a, 6b of between 0.2 and 1 mm. The encapsulation material layers 6a and 6b form an encapsulant assembly preferably chosen to be an ionomer such as the ionomer sold under the name jurasol® ionomer DG3 by the company Jura-plant or the ionomer sold under the name of PV5414 by Du Pont, having a Young's modulus at room temperature greater than or equal to 200 MPa and a thickness of about 500 μm. The second layer 7 forming the rear face of the photovoltaic module 1 is constituted by a polymer material such as thermosetting resins such as epoxy resins, transparent or not, or a composite material, for example of the polymer / fiber type. of glass. In this example, the second layer 7 consists of a composite material of the polymer / glass fiber type, in particular a polypropylene-based fabric and glass fiber with a glass fiber content of 60 15% by weight, such as Thermopreg® fabric P-WRt-1490-PP6OW marketed by Owens Corning Vetrotex, having a thickness of about 1 mm and a Young's modulus at room temperature of about 12 GPa. Moreover, although not shown, a possible adhesive layer, or compatibilizing (its presence being justified in the case of chemical incompatibility), 20 may be located between the second layer 7 forming the rear face of the photovoltaic module 1 and all encapsulant formed by the two layers of encapsulation material 6a and 6b on either side of the assembly 4 of photovoltaic cells 5. This compatibilizing layer may allow the bonding of the second layer 7 to the layer of encapsulating material lower 6b. In the case of using the Thermopreg® fabric P-WRt-1490-PP6OW for the second layer 7, the compatibilizing layer may preferentially be chosen to be a Mondi TK41001 type film having a thickness of about 50 μm. In addition, as can be seen in FIG. 1, the photovoltaic module 1 also comprises an intermediate layer 9 called "damping" layer located between the first layer 3 and the encapsulating assembly formed by the two layers of encapsulation material. 6a and 6b on either side of the set 4 of photovoltaic cells 5. The intermediate layer 9 is optional and finds its main use if there is a chemical incompatibility between the first layer 3 and the layer of material of upper encapsulation 6a. The intermediate layer 9 makes it possible to bond the first layer 3 to the layer of upper encapsulation material 6a. The intermediate layer 9 is for example constituted by a standard encapsulant used in the field of photovoltaics, such as the ethylene-vinyl acetate copolymer (EVA), a polyolefin, silicone, thermoplastic polyurethane, polyvinyl butyral , among others. It may also be constituted by a liquid resin of acrylic, silicone or polyurethane type, one-component or two-component, heat-crosslinkable, photochemically or cold (i.e. at room temperature). It may also consist of a PSA pressure sensitive adhesive (for "Pressure-Sensitive Adhesive"). In this example, the intermediate layer 9 is constituted by a thermoplastic film, namely thermoplastic polyurethane also known by the acronym TPU, such as TPU TPU Dureflex® A4700 sold by the company Bayer or PX1001 marketed by American Polyfilm, 20 of thickness equal to about 380 μm. The intermediate layer 9 serves to fulfill two main functions. On the one hand, it allows the adhesion of the first layer 3 to the upper encapsulation material layer 6a for the case where the two layers are not chemically compatible. On the other hand, it allows to create within the photovoltaic module 1 25 a "damping" layer of a certain flexibility to improve the impact resistance and mechanical loads of the module 1. Moreover, the assembly 10 of Photovoltaic structure according to the invention shown in Figure 1 also comprises a rigid support 2. The rigid support 2 can be of any type of material. It can be flat or curved, smooth or rough.
    [0024] In order to allow the gluing of the photovoltaic module 1 to the rigid support 2, the assembly 10 also comprises a fixing layer 12. This attachment layer 12 is constituted by an adhesion adhesive of the module 1 to the rigid support 2. A method for producing a photovoltaic module 1 and a photovoltaic structure assembly 10 according to the invention will now be described. The method comprises a first step a) of hot rolling at a temperature of about 170 ° C and under vacuum (pressure less than or equal to 10 mbar) of the constituent layers 6a, 4, 6b and 7 of the photovoltaic module 1 except the first Layer 3 and intermediate layer 9. This first rolling step a) is carried out for about 15 minutes so as to obtain a "laminate" of encapsulated photovoltaic cells. The rolling parameters, such as temperature, time and pressure, may however depend on the encapsulant material used. Then, the method comprises a second step b) of hot rolling at a temperature of about 125 ° C. and under vacuum of the "laminate" obtained during the first step a) with the first layer 3 forming the front face of the photovoltaic module 1 using the intermediate layer 9. This second step b) is performed for a period of about 30 minutes to obtain the photovoltaic module 1 according to the invention. Before the implementation of this second step b), the plates 8 of the first layer 3 may advantageously be treated using a Corona treatment equipment so as to obtain a surface energy greater than or equal to 48 dyn / cm. These first a) and second b) rolling steps are then followed by a step of fixing the photovoltaic module 1 on the rigid support 2 which makes it possible to form the photovoltaic structure assembly 10. Therefore, the photovoltaic module 1 according to the invention may have an increased mechanical strength suitable for demanding applications in terms of mechanical stresses, such as the solar road type, but also have a piecewise flexibility due to the presence of a discontinuous front face 3, allowing it to take different forms to adapt to different types of surfaces, for example rough or imperfect flatness. In addition, the presence of a reinforced rear face 7 can make it possible to improve the punching resistance of this rear face 7 of the module 1, this punching being able to result from the roughness of the support 2 on which the module 1 is applied and which can lead 5 of the photovoltaic cells 5 of the photovoltaic module 1. Of course, the invention is not limited to the embodiment which has just been described. Various modifications may be made by the skilled person. The expression "having one" shall be understood as being synonymous with "having at least one", unless the opposite is specified. 10
    权利要求:
    Claims (15)
    [0001]
    REVENDICATIONS1. Photovoltaic module (1) comprising at least: - a transparent first layer (3) forming the front face of the photovoltaic module (1) intended to receive a luminous flux, - an assembly (4) of a plurality of photovoltaic cells (5) disposed side by side and electrically connected to each other, - an encapsulating assembly (6a, 6b) the plurality of photovoltaic cells (5), - a second layer (7) forming the rear face of the photovoltaic module (1), the encapsulant assembly (6a, 6b) and the set (4) of a plurality of photovoltaic cells (5) being located between the first (3) and second (7) layers, characterized in that the first layer (3) consists of at least one transparent polymeric material and comprises a plurality of plates (8) independent of each other, each plate (8) being located facing at least one photovoltaic cell (5), so as to form a discontinuous front face photovoltaic module (1), e in that the rigidity of the encapsulating assembly (6a, 6b) is defined by a Young's modulus (E) of the encapsulation material greater than or equal to 75 MPa at ambient temperature and a thickness (e) of the assembly encapsulant (6a, 6b) of between 0.4 and 1 mm.
    [0002]
    2. Module according to claim 1, characterized in that the encapsulating material of the layers forming the encapsulant assembly (6a, 6b) has a Young's modulus (E) at room temperature greater than or equal to 100 MPa, preferably greater than or equal to 150 MPa, preferably greater than or equal to 200 MPa, in particular equal to 220 MPa. 3024281 22
    [0003]
    3. Module according to claim 1 or 2, characterized in that the second layer (7) forming the rear face of the photovoltaic module (1) consists of at least one polymeric material. 5
    [0004]
    4. Module according to claim 1 or 2, characterized in that the second layer (7) forming the rear face of the photovoltaic module (1) consists of at least one composite material, in particular of the polymer / glass fiber type.
    [0005]
    5. Module according to any one of the preceding claims, characterized in that the rigidity of the second layer (7) forming the rear face of the photovoltaic module (1) is defined by a stiffness factor, corresponding to the Young's modulus ( E) at room temperature of the material of the second layer (7) multiplied by the thickness of the second layer (7), between 5 and 15 GPa.mm. 15
    [0006]
    6. Module according to any one of the preceding claims, characterized in that the spacing (s) between two adjacent photovoltaic cells (5) is greater than or equal to 1 mm, in particular between 1 and 30 mm, and preferably greater or equal to 3 mm, in particular between 10 and 20 mm. 20
    [0007]
    7. Module according to any one of the preceding claims, characterized in that it comprises an intermediate layer (9) called "damping" located between the first layer (3) forming the front face of the photovoltaic module (1) and the encapsulating assembly (6a, 6b) the plurality of photovoltaic cells (5), allowing assembly, in particular by gluing, of the first layer (3) on the encapsulating assembly (6a, 6b).
    [0008]
    8. Module according to claim 7, characterized in that the intermediate layer (9) consists of at least one polymeric material, in particular a thermoplastic or thermosetting polymer resin. 3024281 23
    [0009]
    9. Module according to claim 7 or 8, characterized in that the rigidity of the intermediate layer (9) is defined by a Young's modulus (E) of the material of the intermediate layer (9) less than or equal to 50 MPa at temperature ambient and a thickness of the intermediate layer (9) of between 0.01 and 1 mm. 5
    [0010]
    10. Module according to any one of the preceding claims, characterized in that the thickness of the first layer (3) forming the front face of the photovoltaic module (1) is greater than or equal to 0.1 mm, in particular between 0 , 5 and 6 mm. 10
    [0011]
    Photovoltaic structure assembly (10), comprising: - a rigid support (2), - a photovoltaic module (1) according to any one of the preceding claims, and 15 - an attachment layer (12) located between the support rigid (2) and the photovoltaic module (1), allowing the adhesion of the photovoltaic module (1) to the rigid support (2).
    [0012]
    12. Use, for its application on a rigid support (2) of a photovoltaic module (1) comprising at least: a first transparent layer (3) forming the front face of the photovoltaic module (1) intended to receive a flux luminous, - an assembly (4) of a plurality of photovoltaic cells (5) arranged side by side and electrically connected to each other, - an encapsulating assembly (6a, 6b), the plurality of photovoltaic cells (5), - a second layer (7) forming the rear face of the photovoltaic module (1), the encapsulating assembly (6a, 6b) and the assembly (4) of a plurality of photovoltaic cells (5) being located between the first (3) and second (7) layers, the first layer (3) consisting of at least one transparent polymeric material having a plurality of plates (8) independent of each other, each plate (8) being located opposite to least one photovoltaic cell (5), so that fo radiating a discontinuous front face of the photovoltaic module (1), and the rigidity of the encapsulating assembly (6a, 6b) being defined by a Young's modulus (E) of the encapsulation material greater than or equal to 75 MPa at room temperature and a thickness (e) of the encapsulating assembly (6a, 6b) of between 0.4 and 1 mm, the photovoltaic module (1) being applied to the rigid support (2) via a fixing layer (12). 10
    [0013]
    13. A method of producing a photovoltaic module (1) according to any one of claims 1 to 10, comprising at least two successive steps of: a) hot rolling at a temperature above 150 ° C of 15 l set of layers (6a, 4, 6b, 7) constituting the photovoltaic module (1) except the first layer (3) forming the front face of the photovoltaic module (1) and a possible intermediate layer (9) called "damping", located between the first layer (3) and the encapsulating assembly (6a, 6b) the plurality of photovoltaic cells (5), b) rolling at a temperature strictly lower than or equal to 150 ° C, preferably 125 ° C, the first layer (3) forming the front face of the photovoltaic module (1), and any intermediate layer (9), on the layers (6a, 4, 6b, 7) constituting the photovoltaic module (1) laminated together at the during the first stage a). 25
    [0014]
    14. A method of producing a photovoltaic module (1) according to any one of claims 1 to 10, comprising the single following step of: c) hot rolling at a temperature greater than or equal to 150 ° C of the set of layers (3, 9, 6a, 4, 6b, 7) constituting the photovoltaic module (1). 3024281 25
    [0015]
    15. A method of producing a photovoltaic structure assembly (10) according to claim 11, implementing the steps of the method according to claim 13 or 14, and successively comprising the following step d) of: d) fixing the module photovoltaic system (1) on a rigid support (2) for forming the photovoltaic structure assembly (10) by means of a fixing layer (12) of the photovoltaic structure assembly (10).
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    同族专利:
    公开号 | 公开日
    FR3024281B1|2016-08-26|
    JP2017525153A|2017-08-31|
    KR20170040277A|2017-04-12|
    JP6608910B2|2019-11-20|
    CA2955912A1|2016-02-04|
    EP3175488B1|2018-05-16|
    MA40210A|2016-02-04|
    AU2015295499A1|2017-02-16|
    US20170213925A1|2017-07-27|
    EP3175488A1|2017-06-07|
    WO2016016170A1|2016-02-04|
    AU2015295499B2|2020-10-01|
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    EP1030376A1|1999-02-18|2000-08-23|Sharp Kabushiki Kaisha|Solar cell module and solar cell panel|
    US20080000517A1|2003-06-10|2008-01-03|Gonsiorawski Ronald C|Photovoltaic module with light reflecting backskin|
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    FR3063090A1|2017-02-17|2018-08-24|Commissariat A L'energie Atomique Et Aux Energies Alternatives|PITCHING SYSTEM FOR PIETONS|
    US11223087B2|2017-04-24|2022-01-11|A123 Systems Llc|Structural potting material used to increase crush resistance|
    FR3074823B1|2017-12-13|2019-12-20|Commissariat A L'energie Atomique Et Aux Energies Alternatives|COVERING SLAB FOR FUNCTIONALIZED INFRASTRUCTURE|
    FR3074824B1|2017-12-13|2019-12-06|Commissariat A L'energie Atomique Et Aux Energies Alternatives|FUNCTIONALIZED INFRASTRUCTURE AND METHOD FOR INSTALLING SUCH A FUNCTIONALIZED INFRASTRUCTURE|
    FR3084955A1|2018-08-08|2020-02-14|Commissariat A L'energie Atomique Et Aux Energies Alternatives|METHOD AND SYSTEM FOR DETECTING A LIVING BEING OR AN OBJECT ON A CIRCULAR WAY|
    FR3093116B1|2019-02-26|2021-03-12|Commissariat Energie Atomique|FUNCTIONAL DEVICE INTEGRATED IN A TRAFFIC PAVEMENT|
    法律状态:
    2015-07-31| PLFP| Fee payment|Year of fee payment: 2 |
    2016-01-29| PLSC| Search report ready|Effective date: 20160129 |
    2016-07-29| PLFP| Fee payment|Year of fee payment: 3 |
    2017-07-31| PLFP| Fee payment|Year of fee payment: 4 |
    2018-07-27| PLFP| Fee payment|Year of fee payment: 5 |
    2020-04-10| ST| Notification of lapse|Effective date: 20200306 |
    优先权:
    申请号 | 申请日 | 专利标题
    FR1457277A|FR3024281B1|2014-07-28|2014-07-28|PHOTOVOLTAIC MODULE FOR RIGID SUPPORT|FR1457277A| FR3024281B1|2014-07-28|2014-07-28|PHOTOVOLTAIC MODULE FOR RIGID SUPPORT|
    US15/328,303| US20170213925A1|2014-07-28|2015-07-27|Photovoltaic modules for rigid carriers|
    JP2017504682A| JP6608910B2|2014-07-28|2015-07-27|Photoelectric module for rigid carrier|
    MA040210A| MA40210A|2014-07-28|2015-07-27|Photovoltaic module for a rigid carrier|
    CA2955912A| CA2955912A1|2014-07-28|2015-07-27|Module photovoltaique pour support rigide|
    KR1020177005235A| KR20170040277A|2014-07-28|2015-07-27|Photovoltaic module for a rigid carrier|
    EP15742258.5A| EP3175488B1|2014-07-28|2015-07-27|Photovoltaic module for a rigid carrier|
    AU2015295499A| AU2015295499B2|2014-07-28|2015-07-27|Photovoltaic module for a rigid carrier|
    PCT/EP2015/067116| WO2016016170A1|2014-07-28|2015-07-27|Photovoltaic module for a rigid carrier|
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